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Alcohols, Phenols and Ethers Quiz-6

Dear Readers,

JEE Advanced is a high level exam that checks your concept by putting various types of questions. The questions are in a different format from JEE mains.m, herein the questions are : single correct multiple choice questions, multiple correct multiple choice questions, statement based questions and comprehension type questions..

Q1. 
  •  
  •  
  •  
  •  None
Solution
c



Q2. 
Phenol reacts with PCl5, the main product is:
  •  PhCl
  •  
  •  
  •  
Solution
(d)

Q3. In Zeisel’s method for the determination of methoxyl groups, a sample of 2.68 gm of a compound (A) gave 14.08 gm of AgI. If the molecular weight of compound (A) is 134, the number of (-OCH_3) group (s) in the compound (A) is:
  •  1
  •  2
  •  3
  •  4
Solution
c


Q4. 
  •  
  •  
  •  
  •  
Solution
(b)

Q5.
CH3 OH+C2 H5 OH + H→ products
  •  The product is CH3-O-C2 H5
  •  The product is CH3-O-CH3
  •  The product is C2 H5-O-C2 H5
  •  All
Solution
(d) Intermolecular dehydration of two different 1°alcohols gives a mixture of ethers, ROR,ROR^', and R'OR'

Q6. 
  •  
  •  
  •  
Solution
d

Q7.
Which of the following reactions is possible?
  •  (CH3 )3 C-CH2-ONa+(CH3 )3 C-CH2 Br→(CH3 )3 C-CH2-O-CH2-C(CH3 )3
  •  CH3 CH=CH-ONa+CH3 CH=CH-Br→CH3 CH=CH-O-CH=CH-CH3
  •  (CH3 )3 C-ONa+CH3 CH2 Br→(CH3 )3 C-O-CH2-CH3
  •  CH3 CH2 ONa+PhBr→CH3 CH2 O-Ph
Solution
(c)
a. Not feasible, RX=NeopentylRONa=Neopentyl
b. Not feasible, RX=Vinyl halide,RONa=Vinyl
c. Not feasible, RX=1°RONa=3°
d. Not Feasible, ArX,AONa=1°


Q8.
:
  •  
  •  
  •  
  •  
Solution
(b)

Q9.
  •  
  •  
  •  
  •  All
Solution
(a)

Q10. 

  •  
  •  
  •  
  • All
Solution
(b) Only the acidic ArOH is converted first to its conjugate base then to Me ether

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